Levulinic acid, also known as 4-oxopentanoic acid, is an organic compound that is classified as a keto acid. Its physical form is a white crystalline solid and is soluble in water, ethanol, and diethyl ether, but is insoluble in aliphatic hydrocarbons. In recent years, the need for sustainability has constantly driven the chemical industry towards exploring renewable chemistry and biotechnology to develop products from bio-based sources. These products are developed with the objective of using them as “platforms” for manufacturing a host of industrial and specialty chemicals to replace their synthetic counterparts. Levulinic acid has long since been identified as such a platform chemical. As a result of this, in spite of its relatively small market size, it has been the subject of significant R&D to act as a precursor to specialty chemicals including fuel additives such as Methyltetrahydrofuran (MTHF), pesticides such as D-amino levulinic acid (DALA), Diphenolic Acid (DPA) and so on. The technology to produce bio-based levulinic acid is not very complicated, with the most widely used approach being the dehydrative treatment of biomass or carbohydrates with acid. Other key technologies include hydrolysis of acetyl succinate esters, acid hydrolysis of furfuryl alcohol, and by oxidation of ketones with ozone. Presently, levulinic acid finds applications in pharmaceuticals, pesticides, cosmetics, food additives, and minor uses in nylons, synthetic rubbers, and plastics.
With key raw materials for bio-based levulinic acid being biomass, bagasse, manure, and brewery waste, supply at feasible cost has been a challenge for market participants. Additionally, as with any bio-based replacement chemical, the price has been a burning issue in the levulinic acid market. At current prices ranging between USD 5 per kilo and USD 8 per kilo, manufacturers are faced with a daunting task of matching target prices of close to USD 1 per kilo to penetrate into the downstream platform applications. With a number of R&D initiatives expected to move towards commercialization over the next six years, it is expected that levulinic acid prices shall become more competitive in the coming future. Favorable regulatory scenario and growth in application markets are expected to have a positive influence on levulinic acid demand over the next six years.
The global levulinic acid is likely to grow owing to superior properties of levulinic acid derivatives over their synthetic counterparts. Furthermore, the market is likely to grow on account of the higher product adoption by the consumers. The production of low-cost levulinic acid by the manufacturers in Asia Pacific and Europe is expected to drive market growth.
There are different type of methods of production of levulinic acid. Earlier the production of levulinic acid was cost intensive and the yield which used to form was very less and hence production of levulinic acid was not feasible. However, with emergence of Biofine production process, the formation of levulinic acid became possible using biomass and yield generated by Biofine process is also significantly more as compared to conventional process.
Plasticizer is estimated to emerge as major application segment driving growth of the levulinic acid market. The increase in consumer demand for safe plasticizer and harmful effects on health of phthalate based plasticizer expected to drive the market for levulinic acid over the forecast period. In addition, favorable government policies and regulations towards bio-based plasticizers and stringent regulations on use of phthalates is expected to drive the market growth.
Government policies concerning the production of levulinic acid are favorable owing to the rising environmental concerns and sustainable economic growth. These policies often reflect the strategies related to comparative advantages and the country’s priorities. It aims to develop bioeconomy by promoting public procurement, job generation, and bringing transition from linear to the circular economy.
Levulinic acid market is expected to be restrained by the threat of synthetic chemical alternatives. The market is marked by significant supply and demand gap due to which end users opt for synthetic alternatives of levulinic acid. Synthetic chemical alternatives are easily available and are present in more diverse forms in chemicals market, whereas levulinic acid is a bio-based product and its demand-supply gap does not have high penetration in developing economies.
Levulinic acid producers operate through their manufacturing plants located in closely to raw material source. Moreover, companies involved in the production of levulinic acid and its raw materials are involved in the sales and distribution of the product via a large network of distributors spread across major consuming regions in North America, Asia Pacific, and Europe.
Key application segments analyzed and reported in this study include pharmaceuticals, food additives, cosmetics, and agriculture applications such as Organic potassium fertilizer DALA, 2--Methylindole-3-acetic acid. Presently, levulinic acid is serving niche markets, owing to its high price. Levulinic acid demand for agriculture applications and other pesticides is expected to grow at a CAGR of 6% from 2014 to 2020. Major levulinic acid uses in pharmaceuticals include calcium levulinate and indomethacin, which is a non-steroidal anti-inflammatory drug, prescribed for fever. Levulinic acid demand for pharmaceutical applications is expected to grow at a CAGR of 5.4% from 2014 to 2020. Apart from these applications, levulinic acid is also sparingly used in cigarettes to increase nicotine delivery in smoke and binding of nicotine to neural receptors.
Key downstream potential applications for levulinic acid analyzed and reported in this study include methyltetrahydrofuran (MTHF), delta-aminolevulinic acid (DALA), ethyl levulinate, diphenolic acid (DPA) and others. Commercial scale application for levulinic acid has recently been linked to automobile fuel extenders, primarily MTHF, which is miscible with gasoline in all proportions and displays favorable oxygenate and vapor pressure properties.
Levulinic acid market volume share by application, 2013
Intermediates during the conversion of the levulinic acid to MTHF include γ -Valero lactone (GVL) and 1,4 pentanediol, which are also attractive products in their own right. It is estimated that levulinic acid manufacturers could face a potential demand of over 20,000 kilo tons from MTHF applications by 2020.
North America was the largest levulinic acid consumer in 2013, followed by Europe and the rapidly developing Asia Pacific market. European and U.S. based downstream companies usually source levulinic acid from Chinese manufacturers at low prices for their respective applications. For example, Segetis is reported to be sourcing levulinic acid from China for its L-ketals product portfolio. Europe was the second-largest consumer for levulinic acid in 2012, accounting for over 31% of the global volumes. North America levulinic acid market revenue is expected to grow at a CAGR of 4.6% from 2014 to 2020.
The Europe region has recorded highest growth during the forecast period. Europe emerged as the largest market for levulinic acid and its derivatives, which accounted for 34.7% of the market share in 2018 followed by Asia Pacific which accounted for 22.5% of the market share. The growth in these region can be attributed to favorable government regulations, substantial production capacities, easy availability of raw materials, and early adoption of bio-based chemicals.
Asia Pacific emerged as the second largest market for levulinic acid in 2018 with a market value of USD 2,281.2 million. The region has experienced growing demand for levulinic acid owing to various government policies regarding environmental protection coupled with shift of consumer preferences toward bio-based products. Expanding bio-based plastic industry along with increasing adoption of bio-fuels concepts is projected to drive the growth of the market in Asia Pacific.
Being a leader of industrial biotechnology, the U.S. has a significant share of the levulinic acid market. Implementation of the BioPreferred program by the United States Department of Agriculture (USDA) has fueled the sales of bio-based products, which, in turn, has propelled the demand for levulinic acid in the region. The market in Canada and Mexico is also projected to grow at a healthy rate owing to increasing demand for bio-based products coupled with various government initiatives supporting the production of levulinic acid.
Key market participants for levulinic acid include Segetis, Biofine, DuPont, Hebei Langfang Triple Well Chemicals Co., Ltd., Hebei Shijiazhuang Worldwide Furfural & Furfuryl Alcohol Funan Resin Co., Ltd., Jiangsu Yancheng China Flavor Chemicals Co., Ltd., Shijiazhuang Pharmaceutical Group Ouyi Pharmaceutical Co., Ltd. and Shanghai Apple Flavor & Fragrance Co., Ltd. Biofine has been one of the leading participants in the levulinic acid space, focusing on MTHF and DALA downstream applications. Segetis, a Minnesota-based company, recently developed a molecule on esters of levulinic acid made from corn cobs and bio-based hydroxyl compounds. Levulinic acid is to be used as raw material for the manufacturing of plasticizers, solvents, and polyols for polyurethane foams. Levulinic acid acts as a potential replacement to phthalate plasticizer added to manufacture PVC, the largest consumed commodity plastic.
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The COVID-19 pandemic and subsequent halt in manufacturing activities shall have an impact on the supply availability of a variety of renewable chemicals. Furthermore, current disruption in trade shall also gravely impact the availability of chemical stocks in import-dependent countries. The report will account for Covid19 as a key market contributor.
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